Isam Al Zubaidi*, Justin Gwilliam, Kyle Bachelu, Blake Ackerman, Trevor Ficor and Emma Hulbert
Faculty of Engineering and Applied Science, University of Regina, Canada
*Corresponding author:Isam Al Zubaidi, Industrial System Engineering, Faculty of Engineering and Applied Science, University of Regina, Regina S4S 0A2, Saskatchewan, Canada
Submission: May 8, 2023;Published: June 01, 2023
ISSN 2637-8035Volume5 Issue3
This work is related to the experimental design project requirement for undergraduate students in the Process Engineering Laboratory/Industrial System Engineering Program at the University of Regina /Saskatchewan-Canada for the Heat Mass and Momentum Transfer. This project is to compare the effectiveness and cooling performance of the standard film fill packing material in a water cooling tower apparatus. The results showed that increasing the air and water flow rates can increase efficiency by approximately 10% and 13%, respectively. The cooling ranges and ideal ranges of the cooling tower were used to calculate efficiencies between 83-97% for the regular packing material. Other calculations were performed, including approach, heat and mass transfer coefficients, the heat emitted, mass and energy balance, factorial design analysis using Minitab, Solid Edge work, etc. Many operating variables were evaluated, such as the effect of packing material, flow rates of air and water, water inlet temperature to study the effect of these variable on the efficiency of water cooling towers, which can be used to optimize cooling tower performance in industrial settings.
Keywords:Water cooling tower; Characteristic; Heat and mass transfer coefficient; Design of experiment
Abbreviations:A: Heat Transfer Area (𝑚2); Cp: Specific Heat of Fluid (𝑘𝐽/𝑘𝑔∗𝐾); 𝐺: Mass Flowrate of Air (𝑘𝑔/𝑠); ℎ: Enthalpy of Fluid (𝑘𝐽/𝑘𝑔); 𝐿: Mass Flow Rate of Water (𝑘𝑔/𝑠); 𝐿𝑤: Water Level Height (𝑚3); 𝑚̇: Mass Flowrate of Fluid (𝑘𝑔/𝑠); 𝑄: Amount of Heat Transferred (𝑘𝑊); 𝑞: Flow Rate of Fluid (𝐿/𝑚𝑖𝑛); 𝑞𝑚,𝑙𝑜𝑠𝑠: Rate of Water Loss (𝑘𝑔/𝑠); 𝑞𝑣,𝑙𝑜𝑠𝑠: Rate of Water Loss (𝑚3/𝑠); 𝑇𝑎𝑖𝑟: Temperature of Air (℃); 𝑇𝑤: Temperature of Water (℃); 𝑈: Overall Heat Transfer Coefficient (𝑘𝑊/𝑚2.𝐾); Δ𝑇𝑙𝑚: Log mean temperature difference (℃); 𝜌: Density of Fluid (Kg/m3); K: Mass transfer coefficient (Kg/m2.s); NTU: Number of Transfer Unit
Water is a basic necessity for all living forms on the earth, and it is vital to preserving the cleanliness of the water for sustainability. However, rapid progress in industrial, agricultural, and domestic activities have brought a negative impact on the environment, where large amounts of toxic and hazardous wastes generated by these activities have been discharged into the aquatic system. Contamination of water with these potentially toxic wastes such as heavy metal ions, organic dyes as well as emerging micropollutants which have high toxicity and carcinogenic effect, pose a threat to the aquatic lives as well as bring harmful effects to the ecosystem and human health such as causing severe headaches, diarrhea, skin irritation, cancer, and even death if ingested in sufficient amounts. Hence, industries must handle wastewater with special treatment until it meets the standard before discharge into the river, lakes, or oceans. Several techniques and methods have been applied to remove such pollutants from wastewater, including biological treatment, precipitation, adsorption, membrane filtration, and photocatalytic degradation [1-5].
Nanomaterials with unique properties have been more useful recently, especially in water treatment. Titanium dioxide nanoparticle is a semiconductor with excellent photocatalytic performance and antibacterial properties which has been widely studied and used in the remediation of wastewater. Apart from its photocatalytic and antibacterial properties, it is also non-toxic, environmentally friendly, has low cost, high chemical stability, and readily available which allows it to be the most popular photocatalyst in modifying its composite with other materials to enhance its efficiency and overcome its shortcomings such as the high tendency of agglomeration and low absorption capacity . Clay and clay minerals are also one of the popular classes of materials used in environmental applications due to their high surface area, significant adsorption capacities, environmentally friendly and abundant availability . It has been used in supporting nanoparticles where Titanium dioxide (TiO2) nanoparticles can be loaded on it in order to address and solve the drawbacks of the TiO2 nanoparticles such as poor adsorption capacity, tendency of aggregation, recovery and separation issues . Bentonite is one of the naturally occurring clay minerals, composed of montmorillonite clay which has been gaining high attention and known as the novel bio-sorbent for remediation of contaminated water through adsorption process. It has superior chemical stability, non-toxicity, abundant availability, low cost, high adsorption capacity as compared to other clays, and variety of surface and structural properties . In the recent decades, it has been modified by incorporating different kinds of polymer and nanoparticles to enhance its adsorption capacity for dye removal. Recently,  have constructed a novel alginate/bentonite impregnated TiO2 beads which has shown promising result for removing and degrading the organic dye methylene blue through adsorption and photocatalytic activity simultaneously.
The adsorption and photocatalytic performance of this novel beads are proved to be very efficient where the discoloration of methylene blue is achieved at the rates of 98% during a reduced time of 60min. Moreover, Polyaniline (PANI) based nanocomposite has attracted considerable attention for the removal of aqueous pollutants due to their unique properties such as high surface area, good dispersibility, diverse morphological structures, high environmental stability, low costs of monomer, simple synthesis procedure and unique functional groups that can be easily protonated and deprotonated which is known as the highly reactive adsorption sites that play an important role in its adsorptive properties [9,10]. Various PANI-absorbent for removing various pollutants have been reported such as heavy metal ions, organic dye and emerging pollutants where its morphology, surface area, diverse functional groups as well as the chemical nature of PANIadsorbent often play a role in the adsorption capacities . Currently, we wish to develop a novel innovative approach inn wastewater treatment by synthesizing a novel PANI-TiO2-bentonite nanocomposite for water treatment purposes to remove dye and heavy metal ions from wastewater through double phenomenon of adsorption and photocatalytic processes. Polyaniline and bentonite will function as the support and enhance the adsorption capacities while at the same time increase the photocatalytic process of TiO2 while PANI will reduce the band gap of TiO2 from UV to visible light region.
The excellent established chemical and physical properties of the discussed composites; PANI, TiO2 and Bentonite. The ease of preparations, low market costs, environmental friendliness and high potentiality of applications in different systems is indeed promising in the field of wastewater treatment for the removal of contaminants. Developing a Polyaniline-Titanium Dioxide- Bentonite nanocomposite for removing heavy metal and dyes from wastewater is thus promising and refreshing to researchers in the context of this menace.
© 2023 Mohammad Shahadat. This is an open access article distributed under the terms of the Creative Commons Attribution License , which permits unrestricted use, distribution, and build upon your work non-commercially.