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Research & Development in Material Science

Preparation of Ceramic Humidity Sensors by Electrospinning and Sintering: a Promising Alternative

Evando S Araújo*, Victor N S Leão, Sandy R Monteiro, Ramiro P Guimarães, Allef F R Barbosa and Mayane M Nascimento

Research Group on Electro spinning and Nanotechnology Applications-GPEANano, Federal University of São Francisco Valley, Brazil

*Corresponding author: Evando S Araújo, Research Group on Electrospinning and Nanotechnology Applications (GPEA-Nano), Institute of Materials Science, Federal University of São Francisco Valley, 48902-300, Juazeiro-BA, Brazil

Submission: June 01, 2018; Published: July 02, 2018

DOI: 10.31031/RDMS.2018.06.000647

ISSN: 2576-8840
Volume6 Issue5

Abstract

Humidity is a critical environmental parameter for several production processes and its sensing is of great importance for maintaining the quality of goods and products. This work shows an alternative method for the production of ceramic nanocomposites (using the electro spinning and sintering techniques) for application as humidity sensors.

Keywords: Humidity sensors; Electro spinning; Preparation; Ceramic nanocomposites

Introduction

Humidity is a parameter of great importance for a better quality in the production, storage and transportation of food, goods and medicinal products by industry, among others. In this sense, relative humidity (RH) is the most frequently used parameter for assessing moisture [1]. Humidity sensors are usually made of the polymer or ceramics. Ceramics present superior performance because they have high chemical/structural stability and fast electrical response as a function of RH, operating over a wide range of temperatures. The changes in the electrical response of these sensors are related to the chemisorbed and physisorbed layers of water molecules on the surface of the ceramic particles and to the capillary condensation of water in the microscopic pores between the particles (with the progressive increase of RH) [1]. The selection of oxides, the grain sizes, distribution and shape of the pores, the presence of selective do pants and the production method are decisive factors for producing a device with high sensitivity to humidity [1-3].

In this context, heterogeneous ceramic nanostructures of metallic oxide are materials of great technological interest for the production of more efficient sensors due to excellent electronic and optical properties, high micro structural porosity, regular pore and grain distributions and more reactive surface with water (greater surface area of action/volume) [2,3].

One of the most commonly used metal oxides in humidity sensors is anatase titanium dioxide (TiO2) (~ 3.2eV band gap). Other metal oxides such as zinc oxide (ZnO), copper oxide (CuO), tungsten trioxide (WO3), vanadium pentoxide (V2O5), niobium pentoxide (Nb2O5) and indium oxide (In2O3) have been used as TiO2 do pants. The TiO2:WO3 composition (1:1 in mol) guarantees a higher conductivity over pure TiO2, while do pants such as V2O5 and Nb2O5retard the thermally activated phase transition from anatase to retile TiO2, which favours sensitivity to RH [2,3]. In the last years, these materials have been evaluated as humidity sensors, from a mixture between TiO2 and WO3 doped with V2O5, Nb2O5, ZnO or CuO, in the form of volumetric pellets (length x width x height) [2,3].

Humidity sensors prepared by electro spinning and sintering

An alternative to increase the efficiency of these moisture sensors and decrease the costs to produce them is to further increase the surface area/volume ratio by dispersing the oxides in polymer nanofibers produced by the electro spinning technique and subsequent sintering of the resulting material [4,5]. In the context of this work, initially, the metal oxides are encapsulated in polymer nanofibers through the electro spinning technique (applying a potential difference of 20kV); and then, the resulting material is arranged on an inter digitated electrode and sintered (500 ᵒC) to eliminate the organic phase and obtain the ceramic sensor (Figure 1). Nanofibers act as a polymeric template to ensure adequate distribution of the oxides on the electrode, while the sintering process is used to form heterogeneous ceramic nanostructures with lower band gap, which favours the conduction processes in the material under the action of RH [4,5].

Figure 1:Step by step preparation of humidity sensors by electro spinning and sintering process: (a) oxide nanoparticles into polymer solution for the electro spinning process; (b) electro spun fibers collected as action of a 20kV voltage; (c) layers of fibers disposed on a inter digitated electrode; (d) sintered nanoparticles on a inter digitated electrode (removal of polymeric phase) used as humidity sensor; (e) humidity sensor in a humidity chamber for electrical characterization; and (f) electrical response of the ceramic nanocomposites as function of RH.


In summary, with this new preparation route it is possible to produce thin films of ceramic nanoparticles, using smaller amounts of material than that used to produce disks or pellets, with a larger surface area, without loss of sensorial quality and cheaper. In addition, the electro spinning technique is also promising for moisture sensor production because it offers more advantages such as flexibility in the choice of materials and design, low cost in automation, mass production and good reproducibility of results. The studies also show that the fabrication technique, the sintering temperature and the do pant concentration are decisive factors for increasing the efficiency of the sensors [5].

Conclusion and Perspectives

This work shows to the scientific community the possibility of producing heterogeneous ceramic nanostructures for application as moisture sensors through the electro spinning and sintering techniques. The new preparation route can generate sensors that are more sensitive to variations in moisture when compared to the same materials produced by other methods. The best obtained results characterize the presented proposal as an open field of research for the synthesis and micro structural characterization of these electronic materials for the industry.

Acknowledgement

The authors would like thanks to Dr. Helinando Oliveira and Dr Pedro Faia for their support and teachings.

References

  1. Traversa E (1995) Ceramic sensors for humidity detection: the stateof- the-art and future developments. Sensors and Actuators B: Chemical 23(2-3): 135-156.
  2. Faia PM, Jesus EL, Louro CS (2014) TiO2:WO3 composite humidity sensors doped with ZnO and CuO investigated by impedance spectroscopy. Sensors Actuators B: Chemical 203: 340-348.
  3. Faia PM, Libardi J, Louro CS (2016) Effect of V2O5 doping on p-to-n conduction type transition of TiO2:WO3 composite humidity sensors. Sensors and Actuators B: Chemical 222: 952-964.
  4. Araújo ES, Libardi J, Faia PM, Oliveira HP (2017) Humidity-sensing properties of hierarchical TiO2: ZnO composite grown on electrospun fibers. Journal of Materials Science: Materials in Electronics 28(21): 16575-16583.
  5. Araújo ES, Libardi J, Faia PM, Oliveira HP (2018) Characterization and electrical response to humidity of sintered polymeric electrospun fibers of vanadium oxide-(TiO2/WO3). Journal of Electronic Materials 47(5): 2710-2717.

© 2018 Evando S Araújo . This is an open access article distributed under the terms of the Creative Commons Attribution License , which permits unrestricted use, distribution, and build upon your work non-commercially.