Promises and Challenges: Recent Development of Granular FePt-L10 Thin Film Material for Heat Assisted Magnetic Recording

At room temperature, perpendicularly ordered L10FePt thin film exhibits extremely high uniaxial anisotropy with easy axis oriented along the ordering direction [1]. The relatively low curie temperature and high temperature gradient of the anisotropy field near the Curie point of the L10 FePt makes it almost perfect as a recording media for heat assisted magnetic recording (HAMR) technology [2-5]. In HAMR, an optically (by laser illumination) excited plasmonic near field transducer provides localized electric field to the recording media as schematically shown in Figure 1. The localized alternating electric field at optical frequency generates rapid electronic motion in the metallic magnetic grains of the recording medium underneath, heating up the grains over their Curie temperature. As the medium moves away from the NFT, thereby, the localized electric field, the temperature start to cool down, the medium grains start to regain its magnetization with orientation guided by the recording head field. As the temperature of the medium grains decreases, the magnetic anisotropy of the grains quickly rises. When it exceeds the capability of the recording field, the magnetization direction freezes [6]. In order to insure sharp magnetic transitions between recorded bits, the lateral size of medium magnetic grains needs to be small with thermally insulating grain boundaries. A relatively thick heat sink layer is placed underneath the magnetic layer to facilitate a high thermal gradient, currently at 10K/nm, which is essential to suppress the transition jitter caused by grain-to-grain Curie temperature variation in the media [7-10].


RDMS.000745. 10(4).2019
perpendicular ordering since the c/a ratio of a FePt unit cell becomes smaller than unity when it is ordered in L1 0 phase [11]. This underlayer technique is particularly effective when FePt grain size is relatively small, currently around 7nm, while MgO grain size is relatively large. However, during film deposition process, if a FePt grain grows laterally across a MgO grain boundary, the extension of the lattice coherence in the FePt grain could mean losing the lattice coherence with the neighboring MgO grain underneath. The loss of the tensile stress may cause the portion of the FePt grain on the different MgO grain to order along one of the in-plane directions instead, yielding the grain multi-variant. This multi-variant formation mechanism has been experimentally identified in a systematic nano-diffraction TEM study [12]. To mitigate the effect, using a thick (002) textured Cr or CrRu underlayer beneath the MgO layer to significantly increase MgO grain size has been utilized to reduce the occurrence of such multi-variant grains.
In order to achieve high degree of ordering, FePt-L1 0 granular layer needs to be deposit at elevated substrate temperature during sputtering process, usually above 500 ℃. At such relatively high temperature, it has been very challenge to make the magnetic layer with desired film microstructure: a) Well-defined encircled non-metallic grain boundaries; b) Uniformly distribution of FePt grain size;

c)
Column FePt grain with relatively high aspect ratio (currently grain height to grain diameter ratio is h/D ~2).
Over the past decade, the development of the FePt-L1 0 based HAMR media have been focused on achieving the above three objectives in optimizing microstructure [13]. The fully encircled non-metallic grain boundary is important for thermal isolation to prevent lateral heat flow in maintaining high thermal gradient. Many grain boundary materials have been studied experimentally. Various oxides, such as SiOx, as grain boundary do not produce fully encircled grain boundaries surrounding FePt grains, but rather yield maze-like or worm-like FePt grains. On the other hand, carbon as the grain boundary material has had good success in terms of yielding microstructures with completely encircled FePt grains [14]. FePt grain size can be controlled by the volumetric ratio between carbon and FePt during deposition. However, with carbon as grain boundary material, the nucleation density of FePt grains appears to be limited, preventing reduction of FePt grain pitch to go below 6 nm. Furthermore, carbon grain boundaries do not seem to stop continued FePt grain nucleation on the MgO underlayer during the entire magnetic layer deposition process, resulting relative broad grain size distribution or even bi-modal distribution. The penetration of FePt atoms through carbon grain boundaries during the entire deposition process also yields extensive lateral growth all the way through the depth. The lateral grain growth significantly limits the grain height. More recently, with using alternative grain boundary material, higher height to diameter aspect ratio has been achieved [15]. The ability to produce taller grains with continued reduction of grain size is crucial for suppressing transition jitter caused by thermal agitation during the recording process when temperature is substantially higher than ambient. At small grain sizes, Curie temperature becomes grain size dependent due to significant surface-to-volume ratio with smaller grain diameter having lower Curie temperature. Therefore, a grain size distribution will directly translate into grain-to-grain Curie temperature variation. Such variation can cause significant transition jitter, becoming a limiting factor for linear recording density. Theoretical modelling study shows that the relative standard deviation of Curie temperature distribution needs to be kept below 2% for HAMR to surpass the area density capability of conventional perpendicular magnetic recording (CPMR) [16].
Since the grain size dependence of Curie temperature arises from the fact that atomic spins at grain boundary surface are missing more than half of its neighbours comparing to the spins in the interior of the grains. A thermally insulating magnetic grain boundaries with Curie temperature higher than bulk L1 0 FePt could alleviate the problem provided such grain boundary material will also facilitate the required film microstructure. For this purpose, mixing BaFeO material with carbon as a novel grain boundary material has been investigated by co-sputtering them with FePt [17]. The study found that granular FePt-L1 0 with the mixed grain boundary material exhibits higher Curie temperature than that of pure carbon grain boundaries with the same average FePt grain size as well as reduction of Tc distribution, although small.
Although challenging, the development of FePt-L1 0 granular thin film as HAMR media has made substantial advancement towards the expected area density capability performance [15].